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Copper-Catalyzed Hydrocarboxylation of N -Allenyl Derivatives

Abstract : The addition of carboxylic acids to allenes was performed with copper catalysis. This hydrocarboxylation reaction, occurring on the terminal carbon of the allenes, is totally regio- and stereoselective. It represents the first copper-catalyzed example of intermolecular C–O bond formation by allene hydrofunctionalization. This ligand-free system is based on the use of catalytic amounts of copper combined with a base (10 mol % of K2CO3).
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https://hal.archives-ouvertes.fr/hal-02307629
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Submitted on : Thursday, January 7, 2021 - 11:11:01 AM
Last modification on : Tuesday, February 9, 2021 - 11:24:48 AM

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Rémi Blieck, Marc Taillefer, Florian Monnier. Copper-Catalyzed Hydrocarboxylation of N -Allenyl Derivatives. Journal of Organic Chemistry, American Chemical Society, 2019, 84 (17), pp.11247-11252. ⟨10.1021/acs.joc.9b01510⟩. ⟨hal-02307629⟩

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